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Might not be the best line, more of a situation than the line itself but yes, I consider this to be the best Rachel Green moment in the show.
*Season 8 Episode 1 - The One After ‘I Do’ : Rachel takes a pregnancy test to confirm if she’s actually pregnant.*
Rachel: Oh wait! You know what? I can’t, I can’t look at it. I can’t. Somebody else tell me, somebody tell me.
Phoebe: Umm, it’s negative.
Phoebe: It’s negative.
Rachel: Oh. Oh. Well there you go. Whew! (Pause) That is—that’s great—that is really great-great news. (Pause) Y’know ‘cause the whole not being ready and kinda the financial aspects, all that. Whew. Wow, this is so just the way it was supposed to be. (Starts to cry.) God.
Monica: Well… Well, great.
Phoebe: Here. (Gives Rachel a tissue.)
Rachel: Thanks. (Crying) God this is so stupid! (Pause) How could I be upset over something I never had? It’s negative?
Phoebe: No, it’s positive.
Phoebe: It’s-it’s not negative, it’s positive.
Rachel: Are you sure?
Phoebe: Well yeah, I lied before.
Monica: Oh God..
Phoebe: Now you know how you really feel about it.
Rachel: Oh-oh, that’s a risky little game!
Monica: Are you really gonna do this?
Rachel: Yeah. I’m gonna have a baby. I’m gonna have a baby. I’m gonna have a baby! (They all hug.)